Nanotechnology

Environmental friendly ? – Fe2O3nanoparticles were successfully synthesized via a facile and cost effective chemical precipitation method with the extraction of Nyctanthesarbortristis for the first time. Also it is undergone at room temperature for super capacitor applications and that was observed through electrochemical studies. The prepared samples were characterized by powder X-ray diffraction (XRD), Field emission Scanning electron microscopy (FE-SEM) and UV visible spectroscopic studies. The powder X-ray diffraction study revealed the formation of ? - Fe2O3 in the case of annealed sample. Microscopic images displays that the ? – Fe2O3 nanoparticles were highly agglomerated in nature with the dimension of the order of 2 - 3 ?m. Cyclic voltammetry and simultaneous galvanostatic charge/discharge studies were performed in order to find out the suitability of the material for Supercapacitor applications. The electrochemical results explores that the annealed sample (? – Fe2O3) had improved performance due to its structural with superiority nature. Moreover, the capacitance retention of the ? - Fe2O3 based electrode shows highly stable performance and also its suitability as a lasting electrode material for Super capacitor applications.

Sample pretreatment methods, such as separation / preconcentration prior to the determination of metal ions have developed rapidly due to the increasing need for accurate and precise measurements at extremely low levels of ions in diverse matrices. The development of new sorbents and their application in preconcentration methods for determination of trace analytes is subject of great interest. This review summarizes and discusses several analytical methods involving the preparation and use of new solid phase extractant. A literature survey of the last ten years offering a critical review of these new sorbents available for use in trace analyte enrichment is provided.

 In this research to estimate of the forming energy of Zn-Ferrite were used of the isothermal reaction by using Avrami equation and Avrami Ozawa for Non-Isothermal reaction in use Flow Injection Synthesis reactor, whether as Isothermal or non-isothermal. According the methods above can be obtainedthe formation energy of Zn-Ferrite. In this research have be done four time isothermal experiments at the temperature 60 0C,70 0C and 80 0C respectively. The sampling of experiment data have be done effectively using pH data logger where both pH and temperature were written in SD card memory automaticallyin form Excel format. As a result the formation enthalpy (?H) 4.2 kcal / mol with entropy (S) 12.6 cal / mol deg and 3:14 density gr / cc,respectively

Smooth and adhesive nanocrystalline diamond (NCD) and microcrystalline diamond (MCD) coatings have been achieved on a chemically etched cemented tungsten carbide (WC-6%Co) substrates, using hot filament chemical vapor deposition (HFCVD) technique. Structural and micro-structural characteristics of these coatings were compared using X-ray diffraction (XRD), Raman spectroscopy and Scanning electron microscopy (SEM) techniques. The parameters affecting the integrity of these coating-substrate systems were studied and mathematical analysis was carried out for calculating the force of de-lamination and load bearing capacity.

Enhancement of photocatalytic activity of titania in the visible region and stabilization of anatase phase are significant from the view point of water pollution abatement, since this will enable solar light mediated processes to be scaled up to meet industrial requirements. Recent research has focused on designing nano titania based catalytic systems due to the large surface areas and improved photogeneration of oxidant-reductant species that the nano particles offer. There are several methods for the synthesis of nanoTiO2. Compared to bare TiO2, metal ion doped TiO2 is advantageous, as the doped metal ion alters the band gap and surface adsorption properties. Iron, zinc, cadmium, lanthanum, cerium, cobalt and nickel ions doped TiO2 have been reported in the literature for photocatalytic application. In this context, the present study aims at the co-doping of nano titania with a transition metal ion and a rare earth metal ion. Copper and Samarium ions have been chosen for this purpose as this co-doping has not been reported in the literature so far. In this paper we have synthesized Cu and Sm ions co-doped nano titania prepared by the sol-gel method. This catalyst was characterized by FTIR, XRD, TGA, SEM and UV- visible to analyze the band gap chatacteristics and the effect of calcination on the photodegradation of 4CP

This paper presents two polyester/vinylester blended nanocomposites in which first, blend filled with nanoclay and the second blend filled with nanoiron particles separately and both were reinforced with aramid fibers. Commercially available nanoclay used as it easily for the composite preparation, whereas nanoiron was synthesized using two compounds Fecl3 6H2o and Fecl24H2o under the presence of ammonium using chemical reduction method. The effects of water immersion on mechanical properties as flexural strength, interlaminar shear strength and impact energy of ironnano and nanoclay filled and unfilled quasi-isotropic aramid fibers reinforced polyester/vinylester blended nanocomposites were investigated. Interlaminar shear strength and flexural strength were obtained with the variation of immersion time (0, 95, 155, 195 and 245 days) and weight percent of filler contents viz. (0, 3, 5, and 6wt. %). Impact energy was measured for dry and wet (after conditioning of 245 days) samples as a function of the variation of filler content. Flexural strength, interlaminar shear strength and impact energy increase with increasing filler content in polymer HFRP (hybrid fiber reinforced Plastics) blended nanocomposites. Immersion in water results in a significant increase of flexural strength, interlaminar shears strength and impact energy, increasing with immersion time. Ironnano particles containing HFRP nanocomposites show higher values of flexural strength, interlaminar shear strength and impact energy than those of nanoclay filled and unfilled HFRP blended nanocomposites as ironnano particle settles around the fibers, thus increasing the toughness.

This research will examine synthesis of single-wall carbon nanohorns (SWCNHs) by dielectrophoresis (DEP). This will involve electrokinetic synthesis method which will produce a SWCNHs sensor. In dielectrophoresis (DEP), the carbon particles will be subjected to a non-uniform electric field and thus a force will be exerted on the particles. The materials are dielectrically polarized with electrokinetic motion in non-uniform electric fields. The region of higher electric field will attract the nanoparticles due to positive DEP force. The carbon nanoparticles are then trapped in the electrode gap and thus form an electrical connection to the external measuring circuit. This method provides a fast, simple and low cost fabrication of nanomaterial-based sensors based on a bottom-up approach.

The Au and thiol substituted 2,5-divinylthiophene molecule has been studied for the zero field and various levels of applied external electric fields (EFs) using quantum chemical calculations coupled with AIM theory. The variation in geometrical parameters due to the various external EFs and the corresponding transport properties of the molecule has been analyzed. The variation in MPA and NPA charges, the reduction of HOMO-LUMO gap (from 2.34 to 1.08 eV) and the increase of electric dipole moment (from 0.98 to 13.21 D) with the increase of external EFs (from zero to 0.26 VÅ-1) of the molecule reveals that using thiol as linker and Au as electrodes, 2,5-divinylthiophene molecule can be act as an efficient molecular nanowire.

Quantum dots (QDs) are nanoparticles that have attracted widespread interest in medicine, drug delivery and imaging in living animals due to their unique electronic and optical properties. QDs with Bioconjugated have been introduced for imaging and targeting in living molecular cells, animal models and also in humans. Present efforts are focused on exploring the massive multiplexing capabilities of the QDs for Magnetic resonance imaging (MRI), drug delivery and in addition biocompatibility, bioconjugation and biotoxicity of QDs are also analyzed and discussed. These advances in the QD technology have unraveled a great deal of information about the molecular events in tumor cells and early diagnosis treatment.

Carbon nanotubes fluorescence in a region of the near-infrared, where human tissue and biological fluids are particularly transparent to their emission, but especially in the last decade it has attracted scientific and economic interest triggered by a rapid increase in response to specific biomolecules. A suitable scheme to conjugate the drug and the nanotube is required to make CNTs into viable delivery vehicles. In this present work, multi walled carbon nanotube decorated with titanium dioxide (TiO2-MWNTs) particles have been synthesized and employed as acceptor type materials in organic bulk heterojunction. The donor type material employed in the blend was regioregular poly (3-Octyl Thiophene) (RR-P3OT). X-ray diffraction (XRD), UV-Visible spectroscopy, FT-IR spectroscopy and scanning electron microscopy (SEM) characterized and analyzed.