Effect of substituent and solvent on the electronic spectra of some substituted N-Pheny maaleimide
The effects of substituents and solvents have been studied through the absorption spectra of nearly twelve meta,para and ortho-substituted N-Pheny maaleimide in the range of 200-400 nm. The effects of substituents on the absorption spectra of compounds under investigation are interpreted by correlation of absorption frequencies with simple and extended Hammett equations. With the help of Kamlet equation the effect of solvent polarity and hydrogen bonding on the absorption spectra are interpreted and the results are discussed.
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1142. Effect of varying sizes, colours and time of cured c. nitida nuts on phytochemical content and enzyme activities using botanicals as a preservative material
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Ugioro, O., Ayegboyin, K. O., Idrisu, M., Adeosun, S.A., Nduka, B.A., Baba Nista, M., Okunade, A.F and Oyeledun, K.O. |
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Category : Life Sciences | Sub Category : Applied Botany |
Effect of varying sizes, colours and time of cured c. nitida nuts on phytochemical content and enzyme activities using botanicals as a preservative material
Cola is a tropical tree crop that belongs to the family Sterculiaceae. Phostocin is a preservative chemical used by farmers to store Cola nitida nuts which is considered unsafe to human health when consumed. Fresh C. nitida nuts of different weights (1-10g, 11-20g and above 21g) and colours (pink, red and white) were obtained from Cocoa Research Institute of Nigeria, Ibadan Oyo State. The Nuts were cured for 12weeks with botanicals. These Nuts were oven dried at 700C for 2 days, ground into powder for phytochemical and enzymatic analysis. Data were subjected to Analysis of variance. The leaf of T. grandis had highest values in alkaloid (4.76 g/100g), flavonoid (0.41 g/100g) and theobromine (0.004g/100g) while M. paradisiaca recorded the lowest values for phytochemical analyzed. Cola nitida nuts recorded the highest values in tannin (3.49g/100g), saponin (3.45g/100g), flavonoid (2.46g/100g), anthraquinone (5.19g/100g), caffeine (4.29g/100g) and polyphenol (1.65g/100g) when preserved with T. grandis and the least was obtained for phostocin in red C. nitida nut above 21g. Also, red C. nitida nut above 21g preserved with T. grandis recorded the highest values in catalase (0.154 mg/NaBO3.4H2O/min/g protein), cellulase (0.125 mg/glucose/min/g protein), total amylase (0.141 mg/glucose/min/g protein) and proteinase (0.121 mg/tyrosine/min/g protein) and lowest values obtained in phostocin. Decreased in enzymes activities and phytochemical content were observed in different colours as the number of weeks increases. In conclusion, the use of botanicals as a preservative material to cure kola nuts is better and safe for consumption than phostocin which the farmers are currently using.
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Energy Efficient Packet Transmission-Chain Based Routing Algorithm using Artificial Bee Colony Approach with Multiple Mobile Sinks in WSN
The wide range of transmission medium is covered by the wireless sensor network. Due to its increasing popularity many research are done to increase its energy level for effective transmission. The earliest approach in transferring packets with prior processing is more efficient which used the concept of Ant Colony Optimisation approach to obtain the chain. This existing Power Energy Gathering with Ant colony approach (PEG-ACO) is efficient in minimising transmission distance but there is no mechanism to find out interrupts in transmission, packet loss due to node failure. This paper proposes routing algorithm artificial bee colony approach which optimises the energy level in nodes. The chain is obtained by clustering the nodes with multiple mobile sinks using Artificial Bee Colony (PEG-ABC) concept in order to avoid node failure and packet lost. The load among the nodes is balanced for effective transmission of packets with less energy consumption.
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Enhancing solubility and dissolution of piroxicam by spray drying using Pluronic F127
Piroxicam, an anti-inflammatory drug, exhibits poor water solubility, dissolution and flow properties. Thus, the aim of the present study was to improve the solubility and dissolution rate of Piroxicam by preparing microspheres by spray drying technique. Piroxicam microspheres containing different ratio of F127 were produced by spray drying using dichloromethane as solvent to enhance solubility and dissolution rate. The prepared formulations containing different ratio of drug and polymer were evaluated for in vitro dissolution and solubility. The prepared formulations were characterized by scanning electron microscopy, differential scanning calorimeter, X-ray diffraction and Fourier transform infrared spectroscopy. Dissolution profile of the spray dried microspheres was compared with its physical mixture and pure sample. Spray dried microspheres exhibited decreased crystallinity and the solubility and dissolution of the microspheres containing different ratio of drug and pluronic F127 were significant improved compared with its physical mixture and pure sample of piroxicam. Dissolution of microspheres containing 1:3 w/w (SD 3) showed higher % release i.e. 94 % in 60 min compare to other formulation. Consequently, Hence, From the above result it can be conclude that spray dried microspheres of Piroxicam is a useful technique to improve the solubility and dissolution of poorly water soluble drug like Piroxicam.
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Entropy generation analysis of nanofluid flow in Coiled tube heat exchanger under laminar flow
In this paper analytically investigated the effects of water–Al2O3 nanofluid on the entropy generation through a coiled tube heat exchanger under uniform wall temperature condition in laminar regime. Nanofluid thermo-physical properties are obtained from literature or calculated from suitable correlations. It is found that adding nanoparticles improves the thermal performance of water-Al2O3 flow and with increasing volume constriction of nanoparticle, total entropy generation at fixed Reynolds number, decreases. By increasing , entropy generation decreases, also with increasing , total entropy generation increases.
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Environmental awareness and its impact on behavioural habits of rural and urban population- with special reference to Chidambaram Taluk, Cuddalore Dist. Tamilnadu
All living beings so made that we cannot live in isolation of our environment, our body are made up of all elements available in environment. And any disturbance in purity of environmental component can makes the hazard in our lives. It has posed a great problem to the existence of humans, plant, animal and other form of life on the earth although the prime support for the survival of human being is environment. The process of and side effect of environmental degradation may seems very slow which may not give effect in our life time but will make life of our own next generation miserable. Therefore now there is a need to increase awareness and understanding of the environmental along with responsible attitude toward the sustainable management of environment and natural resources of planet earth. The present study has delimited to study the level of environmental awareness regarding environmental components, services, pollution etc. among the rural and urban respondent of one of the district of Tamilnadu, India. Keywords: Environmental awareness, environmental components, services, pollution, rural and urban.
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Evaluation of environmental monitoring at the Ghana research reactor-1 centre
Regular environmental monitoring has being going on ever since the operation of the Ghana Research Reactor-1 (GHARR-1) to ensure both the safety of the workers in that they are not exposed to any harmful radiations and that equipment’s that are used are in good condition. The objective of this work is to know if the right procedures are being followed to ensure that the minimum radiation dose is not being exceeded as well as not exposing the public to any controlled sources. Moreover over the years there have been encroachers on the Ghana Atomic Energy Commission (GAEC) land and this work therefore seek to know the possible effects these radiations have on those people. From the results obtained 2008 had a range of (0.03-3.10)µSv/h, (0.04-2.71)µSv/h for 2009, (0.07-2.81)µSv/h for 2010 and 2011 also had a range of (0.05-5.64)µSv/h. Comparing to the recommend value (For the public the limit is 1 mSv in a year, or in special circumstances up to 5 mSv in a single year provided that the average dose over five consecutive years does not exceed 1 mSv per year), this shows that the radiations recorded are within the recommended value indicating that the right procedures are being followed. Suffice to say this more work has to be done to ensure that there is a sustainability in following procedures and that the encroachers too must be warned off to avoid any consequences in case there is unavoidable accidents in the near future
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Evaluation of Persica-added Periodontal Pack on Post-Surgical Complications of Periodontal Flap Surgery
Background and Objectives: Periodontal flap surgery to eliminate pockets may result in unpleasant consequences such as pain, bleeding and difficulty in eating. The goal of this study was to evaluate the local application of Persica mouthwash mixed with periodontal dressing for a direct and maximal impact on the surgical wound. Materials & Methods: A split-mouth study design was performed on 30 patients who had moderate to severe chronic periodontitis and were periodontal surgery candidates. The Persica-containing dressing was applied to case side and compared to the dressing containing Serum Physiologic Solution on the control side according to the interdental bleeding index, postoperative pain and discomfort during eating, and the data were analyzed by independent t-test. Results: In all cases evaluated, the Persica mouthwash application brought about more unfavorable results than the control dressing (p? 0.05). Conclusions: addition of Persica mouthwash to periodontal dressing has adverse effects on surgical wound healing and therefore is not recommended.
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Evaluation of physico-chemical and microbiological qualities of drinking water of Benin Republic south aquatic cities
This study focuses on Sô-Ava’s population well-being regarding to drinking water quality especially in the villages of Ahomey- lokpo and Ahomey-ounmey. Samples of water were taken at three kinds of sites (bollard fountains, river sô and shallows) and analysed for searching their physico-chemical and microbiogical characteristics. The differents parameters values obtained are sometimes higher than standards. Indeed for example the averages are ranged from 0,0264mg/L to 0,5247 mg/L for nitrites and from 0,73mg/L to 2,86 mg/L for total iron. Averages microbiological parameters also range in 0-19600 UFC/100mL for faecal coliforms and 42-560 UFC/100mL for total coliforms and finally 0-190 UFC/100mL for faecal streptococcus.
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1150. Evaluation of the severity of African cassava mosaic (AMM) in ten cassava (Manihot esculenta Crantz) clones in relation to the bimonthly leaf harvest in Gbadolite, Democratic Republic of Congo
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Ambwa, J., Idikodingo, T., Molongo, M., Mongbenga, G., Likiti, O., Mambokolo, C., Diko, G., Bulonza, J.C., Empata, L., Ebwa, J., Ugencan, P., Mamba-Mbayi, G., Songbo, M. and Monde, G. |
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Category : Life Sciences | Sub Category : Applied Botany |
Evaluation of the severity of African cassava mosaic (AMM) in ten cassava (Manihot esculenta Crantz) clones in relation to the bimonthly leaf harvest in Gbadolite, Democratic Republic of Congo
Cassava is a staple food in the world and in the Democratic Republic of Congo. A severe cassava epidemic would have long-lasting consequences for the population, which would probably result in malnutrition, reduced work performance, and possible migration to unaffected areas. This situation could be considered a disaster. The purpose of this study was to evaluate the severity of MAM and the bimonthly harvest on the leaf yield of ten cassava (Manihot esculenta Crantz) cultivars in Gbadolite, North Ubangi Province, Democratic Republic of Congo. The experimental design used was that of randomized complete blocks with 3 replications and 10 treatments, or 10 clones. Leaf yields in tons per hectare were 5.2 for cultivar Amuma; 4.1 for cultivars Mado and Moyindo; 3.9 for cultivar TME 419 or Obama; 3.8 for cultivar Nganza; 3.1 for cultivar RAV; 2.9 for cultivars Badiya and Dabeke; 2.7 for cultivar Khadafi and 2.0 for cultivar Yasegumba. MAM infection levels were in the range of 1 for cultivars Amuma and Dabeke; 2 for cultivars Moyindo, TME 419, and RAV; 3 for cultivar Yasegumba; and 4 for cultivars Badiya, Khadafi, Mado or Madame, and Nganza. The one-way analysis of variance and Duncan's test at the 5% probability level showed a significant difference. Tukey's post hoc test grouped cultivars according to the level of MAM infection. These results certify the level of severity of this virus in this province; for this reason, it is advisable to consider the control of this virus by popularizing resistant varieties and adequate cultivation techniques related to it.
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